Their powerful batting line-up, led by Laura Wolvaardt, will fancy their chances of turning the tables on England, who got up to pip them by two wickets with two balls to spare at the same stage in 2017.
Wolvaardt has plundered 433 runs at an average of 61.85 in the tournament, more than any other batter.
The match is due to start at 03:00 SA time on Thursday.
The winner of the clash will face Australia in the final on Sunday, 3 April.
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